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111.
Adhesion of zein to solid substrates has been studied using surface energy profiles as indices and by adhesion mapping using
atomic force microscopy (AFM). Different plasticizers like glycerol and sorbitol have been used to form mixed films with zein
and properties of these films are studied using surface energy profiles. Comparison of the results from the different mixed
samples with those from the pure zein films showed that force mapping could identify areas rich in protein. The adhesion maps
produced were deconvoluted from sample topography and contrasted with the data obtained from contact angle measurements. A
comparison of the two methods shows that the extent of contact angle hysteresis is indicative of both hydrophobicity of the
surface as well as the force of adhesion. Mechanical properties and microstructure of zein films prepared by casting from
solutions and using Langmuir-Blodgett film technique have been investigated. Pure zein seemed brittle and exhibited an essentially
linear relationship between stress and strain. Films with plasticizer were tougher than these films. In general, mixed films
showed better mechanical properties than pure films and had higher ultimate tensile strength and increased per cent elongation.
Further, the mixed films of zein showed a higher force of adhesion compared to the pure films. 相似文献
112.
纳米颗粒悬浮液池内泡状沸腾的实验研究 总被引:7,自引:0,他引:7
本文对纳米颗粒悬浮液在平壁面上池内沸腾进行了实验研究。实验用的纳米粒子为26 nm的铁粉和13 nm的三氧化二铝纳米粉末,基液为去离子水。分别配成体积浓度为0.1%, 1%和2%的悬浮液。实验结果表明,纳米悬浮颗粒对液体沸腾换热过程的影响会随着纳米颗粒性质,颗粒浓度及热流密度大小的不同而出现不同的效果;加入纳米颗粒后, 对基液沸腾换热的影响存在着两个相反的作用机制,它们分别为:纳米颗粒增强了液体内部的热量迁移能力(热物性的影响)和改变了加热面的表面结构特性(加热面特性的影响)。 相似文献
113.
用硼氢化钠作还原剂,制备出两种相对稳定的含银纳米颗粒的水溶胶,用透射电镜(TEM)和光学吸收谱对这些颗粒进行了表征.当被还原的银离子较少时,所形成的银纳米颗粒较小,吸收峰呈现二极等离子体共振吸收峰.当被还原的银离子较多时,银纳米颗粒尺寸变大,并出现二极和四极共振吸收峰.在Ag纳米颗粒形成后,对其溶液稀释,发现其峰形保持不变,而峰位会出现红移,最大红移量可达到10 nm.透射电镜研究表明,低浓度溶胶中的Ag纳米颗粒尺寸较为均匀,平均直径12 nm.高浓度溶胶中的纳米颗粒尺寸呈双尺寸分布特点,少量颗粒直径小于14 nm,大部分颗粒直径大于20 nm. 相似文献
114.
用力敏传感器测量乙醇水溶液的表面张力系数与浓度的关系 总被引:6,自引:3,他引:3
用硅压阻式力敏传感器测量了纯水、乙醇的表面张力系数,并测量了不同浓度的乙醇水溶液的表面张力系数,得到了乙醇水溶液的表面张力系数随浓度的变化曲线. 相似文献
115.
Juan Gonzá lez-Meneses Luis Paris 《Transactions of the American Mathematical Society》2004,356(1):219-243
We show that Vassiliev invariants separate braids on a closed oriented surface, and we exhibit a universal Vassiliev invariant for these braids in terms of chord diagrams labeled by elements of the fundamental group of the surface.
116.
A mathematical model of laser beam treatment of double layer alloys (Ni/Fe, Al/Fe and Cr/Fe systems) describing the effect of laser beam on different physical and geometrical parameters of coated layer system has been adapted. The numerical solutions of the non-homogeneous heat-transport differential equation could estimate the temperature of the treated region.The suggested model allows investigation of the temperature distribution as a function of treated surface and laser parameters. The physical parameters of the treated materials were taken as functions of temperature due to the change in the temperature of the treated double layer materials. 相似文献
117.
An m‐covering of a graph G is a spanning subgraph of G with maximum degree at most m. In this paper, we shall show that every 3‐connected graph on a surface with Euler genus k ≥ 2 with sufficiently large representativity has a 2‐connected 7‐covering with at most 6k ? 12 vertices of degree 7. We also construct, for every surface F2 with Euler genus k ≥ 2, a 3‐connected graph G on F2 with arbitrarily large representativity each of whose 2‐connected 7‐coverings contains at least 6k ? 12 vertices of degree 7. © 2003 Wiley Periodicals, Inc. J Graph Theory 43: 26–36, 2003 相似文献
118.
Andrzej Dabrowski Erich Robens Peter Klobes Klaus Meyer Przemyslaw Podkocielny 《Particle & Particle Systems Characterization》2003,20(5):311-322
Since a comprehensive survey published in 1999 [1] much work was done in standardizing measuring methods to characterize the surface geometry of dispersed and/or porous solids and to certify reference materials. The present paper is an extension of a short communication [2]. It gives a survey on existing standards and reports on new drafts and proposals. 相似文献
119.
120.
Saeed Balalaie Elahe Kowsari Mehri S. Hashtroudi 《Monatshefte für Chemie / Chemical Monthly》2003,134(3):453-456
Summary. Three component condensation of alkylacetoacetates, primary amines, and alkyl cyanoacetates catalyzed by solid supports under
microwave irradiation gave N-alkyl 3-cyano-6-hydroxy-2(1H)-pyridinones with high yields. Upon carrying out the reaction under the same condition on acidic alumina, zeolite HY, silica
gel, and montmorillonite K-10, the best yields were achieved by silica gel.
Corresponding author. E-mail: balalaie@yahoo.com
Received August 28, 2002; accepted September 3, 2002 相似文献